The amp draw isn't split evenly over the batteries. Say its a build thats drawing 40 amps, 20 amps won't be drained for each battery, you don't get to add the amp ratings together. With dual 20 amp batteries your maximum cdr for the mod will be closer to 30 amps.
LG HG2's are great batteries but more geared toward regulated mods. They won't be able to push out as much voltage as other cells while under load, basically they won't hit as hard. Below a video showing the graphed results of their discharge current compared to a couple other popular choices.
OP, you will be better suited using samsung 25r's due to their higher mah rating, however if you build lower in a parallel box I think you will be better suited with the sony vtc4.